Showing posts with label materials. Show all posts
Showing posts with label materials. Show all posts

July 05, 2008

Creating strong macroscale Carbon nanotube material


Back in 2006, then Los Alamos researcher Yuntian Zhu was making 4 centimeter long strands of carbon nanotubes and was talking about forming Superthreads out of it with 100 times the strength of steel. The actual GPa strength was not mentioned in the online article.

Yuntian Zhu is now at NC State and is now making shorter arrays of carbon nanotubes This research paper does mention that the tensile strength and stiffness of these CNT fibers were measured in the range 1.35 to 3.3 GPa and 100 to 263 GPa, respectively. CNT fibers have an extremely low density, (0.2 ± 0.01) g cm–3, which is one-tenth the density of a commercial carbon fiber and about one-fortieth the density of steel. Yuntian is working with CNT Technologies to commercialize this material.

This equals 6.5 to 16.5 GPa g/cc.

They calculated the toughness (the work needed to break the fiber) of a CNT fiber as (975 ± 49) J g–1, which is comparable to the toughness of a recently reported single-walled nanotube/poly(vinyl alcohol) (SWNT/PVA) composite fiber (870 J g–1);[15] higher than the toughness of a similar fiber reported previously (570 J g–1);[13] and much higher than carbon fibers(12 J g–1), Kevlar fibers (33 J g–1), and CNT fibers reported previously (14–20 J g–1). The toughness of Zhu's CNT fibers ranged from (110 ±5) to (975 ± 49) J g–1.



From a April, 2008 paper Zhu discusses growth of ultralong (4.7 mm) double wall carbon nanotube (DWCNT) arrays.

The growth of long spinnable arrays has already led to the production of nanotube fibers that are much stronger per weight than any current engineering material or fiber. We expect to grow even longer spinnable nanotube arrays for spinning stronger nanotube fibers (yarns).

An online patent discusses the work and processes

A space elevator site is tracking the progress of carbon nanotubes toward the creation of suitable space elevator tethers.

In recent documents by other researchers:
In 2008, 40 GPa g/cc from Sparse (Carbon nanotubes) CNT Composite was made.

"The extraordinary reinforcing efficiency of single-walled carbon nanotubes in oriented poly(vinyl alcohol) tapes", Wang et al. IOP Nanotechnology vol. 18 –
inferred strength of SWNTs from a 1% CNT reinforced plastic tape.

In 2007, 9 GPa g/cc strenth material for millimeter lengths

"High-Performance Carbon Nanotube Fiber", Krzysztof Koziolet al, Science Magazine, 2007 - Measurement of the strongest of a sample of mm-long pure aggregated carbon nanotube fibers.

Goal 2010, 35 GPa g/cc for 1000 km x mm

Minimal value for Space Elevator ribbon, Taper Ratio=6.3 with 33% safety factor.
Comparative Ribbon Mass = 4.6 - May require more efficient power system.

Goal 2011, 50 GPa g/cc for 1000 km x mm

Basic value for Space Elevator ribbon, Taper Ratio=3.5 with 33% safety factor.
Comparative Ribbon Mass = 2.0

Goal 2012, 80 GPa g/cc for 1000 km x mm

Desirable value for Space Elevator ribbon, Taper Ratio=2.5 with 50% safety factor.
Comparative Ribbon Mass = 1.0

The 2008 work by Z Wang is getting a follow up navy study for increased percentages of carbon nanotubes in plastic

This STTR requests proposals that develop a clear scientific understanding of the main obstacles to ultrahigh CNT loading in nanocomposites and that proposes new methods or approaches to increasing the loading of well dispersed CNTs in structural resins beyond 10% weight fraction.



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June 27, 2008

Nanostructure copper interfaces for enhanced boiling


Koratkar and his team found that by depositing a layer of copper nanorods on the surface of a copper vessel, the nanoscale pockets of air trapped within the forest of nanorods "feed" nanobubbles into the microscale cavities of the vessel surface and help to prevent them from getting flooded with water. This synergistic coupling effect promotes robust boiling and stable bubble nucleation, with large numbers of tiny, frequently occurring bubbles.

"By themselves, the nanoscale and microscale textures are not able to facilitate good boiling, as the nanoscale pockets are simply too small and the microscale cavities are quickly flooded by water and therefore single-use," Koratkar said. "But working together, the multiscale effect allows for significantly improved boiling. We observed a 30-fold increase in active bubble nucleation site density — a fancy term for the number of bubbles created — on the surface treated with copper nanotubes, over the nontreated surface."

Boiling is ultimately a vehicle for heat transfer, in that it moves energy from a heat source to the bottom of a vessel and into the contained liquid, which then boils, and turns into vapor that eventually releases the heat into the atmosphere. This new discovery allows this process to become significantly more efficient, which could translate into considerable efficiency gains and cost savings if incorporated into a wide range of industrial equipment that relies on boiling to create heat or steam.




Caption: A scanning electron microscope shows copper nanorods deposited on a copper substrate. Air trapped in the forest of nanorods helps to dramatically boost the creation of bubbles and the efficiency of boiling, which in turn could lead to new ways of cooling computer chips as well as cost savings for any number of industrial boiling application. Credit: Rensselaer Polytechnic Institute/ Koratkar


The team's discovery could also revolutionize the process of cooling computer chips. As the physical size of chips has shrunk significantly over the past two decades, it has become increasingly critical to develop ways to cool hot spots and transfer lingering heat away from the chip. This challenge has grown more prevalent in recent years, and threatens to bottleneck the semiconductor industry's ability to develop smaller and more powerful chips.

Boiling is a potential heat transfer technique that can be used to cool chips, Koratkar said, so depositing copper nanorods onto the copper interconnects of chips could lead to new innovations in heat transfer and dissipation for semiconductors.



FURTHER READING
Supporting material for the research paper

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Advances toward quantum control: better trapped ion quantum gates, hybrid molecules in silicon, quantum coral


The new molecule is a hybrid, with the naturally occurring arsenic at one end in a normal spherical shape and a new, artificial atom at the other end in a flattened, 2-D shape. By controlling the voltage, the researchers found that they could make an electron go to either end of the molecule or exist in an intermediate, quantum, state.


Progress toward gate model Quantum Computer components with new molecule with more easily controlled quantum properties

"Our experiment made us realize that industrial electronic devices have now reached the level where we can study and manipulate the state of a single atom," Rogge says. "This is the ultimate limit, you can not get smaller than that."

Physicist Lloyd Hollenberg and colleagues at the University of Melbourne in Australia were able to construct a theoretical silicon-based quantum computer chip based on the concept of using an individual impurity.

"The team found that the measurements only made sense if the molecule was considered to be made of two parts," Hollenberg says. "One end comprised the arsenic atom embedded in the silicon, while the 'artificial' end of the molecule forms near the silicon surface of the transistor. A single electron was spread across both ends.

"What is strange about the 'surface' end of the molecule is that it occurs as an artifact when we apply electrical current across the transistor and hence can be considered 'manmade.' We have no equivalent form existing naturally in the world around us."

Klimeck, along with graduate student Rajib Rahman, developed an updated version of the nano-electronics modeling program NEMO 3-D to simulate the material at the size of 3 million atoms.


In a Nature Physics journal paper currently online, the researchers describe how they have created a new, hybrid molecule in which its quantum state can be intentionally manipulated - a required step in the building of quantum computers.

"Up to now large-scale quantum computing has been a dream," says Gerhard Klimeck, professor of electrical and computer engineering at Purdue University and associate director for technology for the national Network for Computational Nanotechnology.

"This development may not bring us a quantum computer 10 years faster, but our dreams about these machines are now more realistic."


Fault tolerant Trapped ion quantum gate

Towards fault-tolerant quantum computing with trapped ions

Ion traps are among the most promising physical systems for constructing a quantum device harnessing the computing power inherent in the laws of quantum physics. For the implementation of arbitrary operations, a quantum computer requires a universal set of quantum logic gates. As in classical models of computation, quantum error correction techniques enable rectification of small imperfections in gate operations, thus enabling perfect computation in the presence of noise. For fault-tolerant computation, it is believed that error thresholds ranging between 10**-4 and 10**-2 will be required—depending on the noise model and the computational overhead for realizing the quantum gates—but so far all experimental implementations have fallen short of these requirements. Here, we report on a Mølmer–Sørensen-type gate operation entangling ions with a fidelity of 99.3(1)%. The gate is carried out on a pair of qubits encoded in two trapped calcium ions using an amplitude-modulated laser beam interacting with both ions at the same time. A robust gate operation, mapping separable states onto maximally entangled states is achieved by adiabatically switching the laser–ion coupling on and off. We analyse the performance of a single gate and concatenations of up to 21 gate operations.


Changing the properties of a Quantum Corral by changing one atom


Single-atom gating of quantum-state superpositions

Unprecedented control over the superposition of electronic states of a 'quantum corral', by changing the position of a single atom within it, provides a powerful tool for studying the quantum behaviour of matter. Quantum corral are discussed in creating quantum mirages

Work by Chris Moon and others at Stanford working in the Manipulating the Atom group

The ultimate miniaturization of electronic devices will probably require local and coherent control of single electronic wavefunctions. Wavefunctions exist within both physical real space and an abstract state space with a simple geometric interpretation: this state space—or Hilbert space—is spanned by mutually orthogonal state vectors corresponding to the quantized degrees of freedom of the real-space system. Measurement of superpositions is akin to accessing the direction of a vector in Hilbert space, determining an angle of rotation equivalent to quantum phase. Here, we show that an individual atom inside a designed quantum corral1 can control this angle, producing arbitrary coherent superpositions of spatial quantum states. Using scanning tunnelling microscopy and nanostructures assembled atom-by-atom2, we demonstrate how single spins and quantum mirages3 can be harnessed to image the superposition of two electronic states. We also present a straightforward method to determine the atom path enacting phase rotations between any desired state vectors. A single atom thus becomes a real-space handle for an abstract Hilbert space, providing a simple technique for coherent quantum-state manipulation at the spatial limit of condensed matter.


FURTHER READING
Publications of Jan Benhelm

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June 26, 2008

New permanent near terabit per square inch computer memory


Capacitors in the mask: Thanks to a 100 nm thin mask made of aluminum oxide (above), the German and Korean research team were able to trickle the ceramic (PZT) onto the platinum layer (Pt). The scientists then cut off some platinum to create electrical contact to the ceramic. Image: Max Planck Institute of Microstructure Physics

Individually addressable epitaxial ferroelectric nanocapacitor arrays with near Tb inch- 2 density that could displace current computer memory Permanent high density memory.

Woo Lee1, Hee Han Andriy Lotnyk, Markus Andreas Schubert, Stephan Senz, Marin Alexe, Dietrich Hesse, Sunggi Baik & Ulrich Gösele1

of

- Max Planck Institute of Microstructure Physics, Weinberg 2, D-06120 Halle, Germany
- Department of Materials Science & Engineering, Pohang University of Science and Technology, San 31, Hyoja-dong, 790-784 Pohang, Korea
- Korea Research Institute of Standards and Science (KRISS), Yuseong, 305-340 Daejon, Korea

Ferroelectric materials have emerged in recent years as an alternative to magnetic and dielectric materials for nonvolatile data-storage applications. Lithography is widely used to reduce the size of data-storage elements in ultrahigh-density memory devices. However, ferroelectric materials tend to be oxides with complex structures that are easily damaged by existing lithographic techniques, so an alternative approach is needed to fabricate ultrahigh-density ferroelectric memories. Here we report a high-temperature deposition process that can fabricate arrays of individually addressable metal/ferroelectric/metal nanocapacitors with a density of 176 Gb inch- 2. The use of an ultrathin anodic alumina membrane as a lift-off mask makes it possible to deposit the memory elements at temperatures as high as 650 °C, which results in excellent ferroelectric properties.


The permanent memory produced through the German-Korean cooperation can save 176 billion bits per square inch, which is 27 billion bits per square centimeter - more than any comparable memory made of this type of material. "We are approaching memory density of several terabits or billions of bits per square inch, and we hope to be able to increase the memory density even further," relates Dietrich Hesse. Such high memory density is necessary for more widespread use of permanent memory. They could, for example, make the hard-drive and tedious booting up of computers a thing of the past.

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three-dimensional nanoscale structures of magnetic metals could make new classes of MEMS devices


Click on the picture for a larger image. Working in the trenches: Transmission electron microscopy image of a thin cross section of 160 nanometer trenches shows deposited nickel completely filling the features without voids. (Color added for clarity.)

Materials scientists at the National Institute of Standards and Technology (NIST) have developed a process to build complex, three-dimensional nanoscale structures of magnetic materials such as nickel or nickel-iron alloys using techniques compatible with standard semiconductor manufacturing. The process, described in a recent paper, could enable whole new classes of sensors and microelectromechanical (MEMS) devices.

The NIST team also demonstrated that key process variables are linked to relatively quick and inexpensive electrochemical measurements, pointing the way to a fast and efficient way to optimize the process for new materials.

The NIST process is a variation of a technique called “Damascene metallization” that often is used to create complicated three-dimensional copper interconnections, the “wiring” that links circuit elements across multiple layers in advanced, large-scale integrated circuits. Named after the ancient art of creating designs with metal-in-metal inlays, the process involves etching complex patterns of horizontal trenches and vertical “vias” in the surface of the wafer and then uses an electroplating process to fill them with copper. The high aspect ratio features may range from tens of nanometers to hundreds of microns in width. Once filled, the surface of the disk is ground and polished down to remove the excess copper, leaving behind the trench and via pattern.

The big trick in Damascene metallization is ensuring that the deposited metal completely fills in the deep, narrow trenches without leaving voids. This can be done by adding a chemical to the electrodeposition solution to prevent the metal from building up too quickly on the sides of the trenches and by careful control of the deposition process, but both the chemistry and the process variables turn out to be significantly different for active ferromagnetic materials than for passive materials like copper. In addition to devising a working combination of electrolytes and additives to do Damascene metallization with nickel and a nickel-iron alloy, the NIST team demonstrated straightforward measurements for identifying and optimizing the feature-filling process thereby providing an efficient path for the creation of quality nanoscale ferromagnet structures.


C.H. Lee, J.E. Bonevich, J.E. Davies and T.P. Moffat. Magnetic materials for three-dimensional Damascene metallization: void-free electrodeposition of Ni and Ni70Fe30 using 2-mercapto-5-benzimidazolesulfonic acid. Journal of The Electrochemical Society, 155 (7) D499-D507 (2008).

The new process makes it feasible to create complex three-dimensional MEMS devices such as inductors and actuators that combine magnetic alloys with non-magnetic metallizations such as copper interconnects using existing production systems.

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June 25, 2008

Approximate visible light cloak simulated and practical device within reach


Silicon photonic crystal has holes of the right sizes and waveguides

In computer simulations, the researchers have demonstrated an approximate cloaking effect created by concentric rings of silicon photonic crystals. The mathematical proof brings scientists a step closer to a practical solution for optical cloaking.

"This is much more than a theoretical exercise," said Harley Johnson, a Cannon Faculty Scholar and professor of mechanical science and engineering at Illinois. "An optical cloaking device is almost within reach."

Axisymmetric photonic crystal structures may be designed to possess interesting optical properties, particularly when the photonic band structure of the material is highly anisotropic. We use finite element calculations to demonstrate an approximate electromagnetic cloaking effect imparted by a structure consisting of concentric silicon photonic crystal layers. The results show that it is possible to bend light around an object by simply using anisotropy. The calculations show that the cloaking mechanism is fundamentally different from Pendry's approach. This design may work as a practical solution for optical cloaking.


D. Xiao and H. T. Johnson, “Approximate cloaking effect in an axisymmetric silicon photonic crystal structure,” Optics Letters, 33, 860-862 (2008).


In October 2006, an invisibility cloak operating in the microwave region of the electromagnetic spectrum was reported by researchers at Duke University, Imperial College in London, and Sensor Metrix in San Diego. In their experimental demonstration, microwave cloaking was achieved through a thin coating containing an array of tiny metallic structures called ring resonators.

To perform the same feat at much smaller wavelengths in the visible portion of the spectrum, however, would require ring resonators smaller than can be made with current technology, Johnson said. In addition, because metallic particles would absorb some of the incident light, the cloaking effect would be incomplete. Faintly outlined in the shape of the container, some of the background objects would appear dimmer than the rest.

To avoid these problems, postdoctoral research associate Dong Xiao came up with the idea of using a coating of concentric rings of silicon photonic crystals. The width and spacing of the rings can be tailored for specific wavelengths of light.

"When light of the correct wavelength strikes the coating, the light bends around the container and continues on its way, like water flowing around a rock," Xiao said. "An observer sees what is behind the container, as though it isn't there. Both the container and its contents are invisible."

Currently simulated in two dimensions, the cloaking concept could be extended to three dimensions, Xiao said, by replacing the concentric rings with spherical shells of silicon, separated by air or some other dielectric.

The researchers' optical cloaking technique is not perfect, however. "The wave fronts are slightly perturbed as they pass around the container," said Johnson, who also is affiliated with the university's Beckman Institute and the Frederick Seitz Materials Research Laboratory. "Because the wave fronts don't match exactly, we refer to the technique as 'approximate' cloaking."



FURTHER READING

Invisibility to sound for acoustic shields (hide nuclear deterrent submarines from sonar detection) and shaping sound and other waves (like earthquakes) is also coming soon

Researchers at the University of Illinois are the first to achieve optical waveguiding of near-infrared light through features embedded in self-assembled, three-dimensional photonic crystals. Applications for the optically active crystals include low-loss waveguides, low-threshold lasers and on-chip optical circuitry.

Harley Johnson site

Photonic crystal tutorial

Silicon photonic crystal

Scanning electron micrograph of a porous silicon photonic crystal

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June 24, 2008

Space elevator games and Lunar lander contest 2008 preview


The Space elevator power beaming (climber) competition is on Sept 27, 2008

Vertical Distance: 1 kilometer (ten times the 2007 distance)
Speed for prizes: 2 m/s for $900,000 and 5 m/s for $2 million

11 teams have entered the 2008 power beaming / climbing contest

The University of Saskatchewan space design team
The University of Saskatchwan team almost won in 2007
University of Alberta racing team
Queen's space elevator team
McGill Space elevator team

Kansas City Space Pirates
MClimber from Michigan
NSS Space elevator team
Laser Motive
TXL group

Team Nippon
Earth track controllers


Proving Space Elevator components by 2010
The Space Elevator requires two major achievements: a tether which is at least 30 GPa-cc/g strong (see below), and a long-range power beaming system in the Mega-Watt range.
The Spaceward foundation plan to demonstrate by the year 2010, a 10 GPa-cc/g CNT tether, and a multi-kWatt km-scale power beaming demonstration.

With these benchmarks demonstrated, the Spaceward Foundation plans to pursue a 5-year development phase (phase 1) of full-performance components, followed by a 5-year system development effort (phase 2). This puts the beginning of construction (phase 3) around the year 2020.


Tether strength to weight ratio seems to be on track to reach the necessary levels by 2013.

In 2007, 9 GPa g/cc strenth material for millimeter lengths

"High-Performance Carbon Nanotube Fiber", Krzysztof Koziolet al, Science Magazine, 2007 - Measurement of the strongest of a sample of mm-long pure aggregated carbon nanotube fibers.

In 2008, 40 GPa g/cc
from Sparse (Carbon nanotubes) CNT Composite

"The extraordinary reinforcing efficiency of single-walled carbon nanotubes in oriented poly(vinyl alcohol) tapes", Wang et al. IOP Nanotechnology vol. 18 –
inferred strength of SWNTs from a 1% CNT reinforced plastic tape.

Abstract. This paper reports on oriented poly(vinyl alcohol)/single-walled carbon nanotube (PVA/SWNT) tapes that were prepared by a mild processing route, involving the use of dimethyl sulfoxide (DMSO) as a solvent. Composite films with homogeneously dispersed SWNTs were cast from solution and drawn into oriented tapes using solid-state drawing. The obtained tapes showed the extraordinary reinforcing effects of the SWNTs, as the addition of 1.0 wt% SWNTs tripled the tensile strength of the PVA tapes. Micromechanical analysis showed that the nanotube contribution to the composite strength was as high as 88 GPa, which is very high when compared to other data reported in the literature, and for the first time begins to exploit the theoretical strength of nanotubes.


Goal 2010, 35 GPa g/cc for 1000 km x mm

Minimal value for Space Elevator ribbon, Taper Ratio=6.3 with 33% safety factor.
Comparative Ribbon Mass = 4.6 - May require more efficient power system.

Goal 2011, 50 GPa g/cc for 1000 km x mm

Basic value for Space Elevator ribbon, Taper Ratio=3.5 with 33% safety factor.
Comparative Ribbon Mass = 2.0

Goal 2012, 80 GPa g/cc for 1000 km x mm

Desirable value for Space Elevator ribbon, Taper Ratio=2.5 with 50% safety factor.
Comparative Ribbon Mass = 1.0

The 2008 work by Z Wang is getting a follow up navy study for increased percentages of carbon nanotubes in plastic

This STTR requests proposals that develop a clear scientific understanding of the main obstacles to ultrahigh CNT loading in nanocomposites and that proposes new methods or approaches to increasing the loading of well dispersed CNTs in structural resins beyond 10% weight fraction.


The Lunar Lander contest is October 24-25, 2008
There was almost a winner in 2007 and 2006. There should be a winner in 2008.


FURTHER READING
Space Elevator conference Friday, July 18 thru Sunday, July 20 in Redmond Washington

2nd European climber workshop - Luxembourg - October 18 thru October 19. 2008

1st Japanese space elevator conference Nov 2008

Wikipedia on the space elevator

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June 23, 2008

Impossible control of number electrons on the surface of a superconductor made real

A team of University of British Columbia researchers has developed a technique that controls the number of electrons on the surface of high-temperature superconductors, a procedure considered impossible for the past two decades.

Led by Physics Assoc. Prof. Andrea Damascelli, the team deposited potassium atoms onto the surface of a piece of superconducting copper oxide. The approach allows the scientists to continuously manipulate the number of electrons on ultra-thin layers of material. This level of control of electrons on surfaces will have applications beyond superconductors to other materials.

From the Nature Physics paper:In situ doping control of the surface of high-temperature superconductors

Central to the understanding of high-temperature superconductivity is the evolution of the electronic structure as doping alters the density of charge carriers in the CuO2 planes. Superconductivity emerges along the path from a normal metal on the overdoped side to an antiferromagnetic insulator on the underdoped side. This path also exhibits a severe disruption of the overdoped normal metal's Fermi surface. Angle-resolved photoemission spectroscopy (ARPES) on the surfaces of easily cleaved materials such as Bi2Sr2CaCu2O8+ shows that in zero magnetic field the Fermi surface breaks up into disconnected arcs. However, in high magnetic field, quantum oscillations at low temperatures in YBa2Cu3O6.5 indicate the existence of small Fermi surface pockets. Reconciling these two phenomena through ARPES studies of YBa2Cu3O7- (YBCO) has been hampered by the surface sensitivity of the technique. Here, we show that this difficulty stems from the polarity and resulting self-doping of the YBCO surface. Through in situ deposition of potassium atoms on cleaved YBCO, we can continuously control the surface doping and follow the evolution of the Fermi surface from the overdoped to the underdoped regime. The present approach opens the door to systematic studies of high-temperature superconductors, such as creating new electron-doped superconductors from insulating parent compounds.


UPDATE: The Vancouver Sun reports on the steps used

First, the copper oxide is put in a stainless-steel chamber kept in "outer space vacuum conditions" to avoid contaminating the sample, Damascelli explained. Atoms of potassium are then deposited onto the sample's surface, leaving behind electrons.

The second trick involves a technique that goes back to Albert Einstein's Nobel Prize-winning research into the photoelectric effect. Researchers shine light on the sample, which is absorbed by the electrons and ejected from the sample in a way that can be measured.

"This study that we do is the only way to really understand what is happening inside the superconductor," Damascelli said.

The experiment is groundbreaking for two reasons: Scientists are now able to control the number of electrons on the surface of a superconductor, and can also observe them.


"Extremely thin layers and surfaces of superconducting materials take on very different properties from the rest of the material. Electrons have been observed to re-arrange, making it impossible for scientists to study," says Damascelli. "It's become clear in recent years that this phenomenon is both the challenge and key to making great strides in superconductor research.

"The new technique opens the door to systematic studies not just of high-temperature superconductors, but many other materials where surfaces and interfaces control the physical properties," says Damascelli. "The control of surfaces and interfaces plays a vital role in the development of applications such as fuel cells and lossless power lines, and may lead to new materials altogether."

The superconductors Damascelli's team experimented on are the purest samples currently available and were produced at UBC by physicists Doug Bonn, Ruixing Liang and Walter Hardy.

Part of the study was carried out at the Advanced Light Source synchrotron in California. In the future, the design and study of novel complex materials for next-generation technologies will be carried out at the Quantum Materials Spectroscopy Center currently under construction at the Canadian Light Source in Saskatoon under Damascelli's leadership.


FURTHER READING
Profile of Andrea Damascelli

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June 19, 2008

Achieving a Mundane Technological Transhuman Singularity

Some people have criticized the technological Singularity and Transhumanism because of the upside being things that they do not believe can be achieved.Also, the primary technologies that are often described as enabling the Singularity and Transhumanism are Molecular Nanotechnology and greater than human intelligence general AI. There has been virtually no effort or money spent to develop diamondoid molecular nanotechnology and greater than human AGI is something that will be a rapid shift. For AGI, one can imagine the situation before Deep Blue beat Gary Kasparov in chess. A couple of years before it happened many people thought it would be long time before a computer won at chess and many were surprised when it did happen.

This site does not agree that Molecular Nanotechnology (MNT) is not achievable or that greater than human intelligence AI is not achievable. However, let us examine how some of the primary Singularity and Transhuman goals can be achieved even without Molecular Nanotechnology or greater than human intelligence AGI.

The goals, with the first blurb the term used by a critic (Richard Jones for the first three and then goals many have derided for the later goals) and goals from Eric Drexler's website related to MNT, and what follows as a more detailed description of a precise and measurable goal.
1. End scarcity : Relative economic abundance with every living person having an personal resources at the affluent level of a current US citizen. $250,000 per person per year in purchasing power parity income. [The income level that Obama would want to tax more heavily if he become President]. No shortages of any basic need water, food, medical care [equal to that which is achieving the medical results currently affordable to an affluent person now] and energy [currently a US citizen uses an average of 13,000 kwh per year for electricity and three times that for transportation and a share of industrial energy usage. So abundance is 100,000 kwh for every person and assuming a future population of 10 billion is 1000 trillion kwh.

A manufacturing and construction revolution can be achieved with printable buildings, inflatable electric cars, printable electronics and advanced automated rapid manufacturing.


Computer simulation and detailed modeling and other enabling technology will enable the revolution.

Paper stronger than cast iron made from plant cellulose is here and will make manufacturing far cheaper.

Stem cell meat factories, advanced aquaculture and vertical farming and more advanced genetically engineered food will enable an abundance of food. The vertical farming would be further enabled by the printing building technology.

Aquaculture (fish farming) already provide over half of the world's fish.


For water desalination is already very advanced and it is becoming more energy efficient and cheaper. More abundant and affordable energy helps to create more water from desalinization.

The mass produced uranium hydride nuclear reactor would be part of a relatively mundane energy abundance solution. These reactors would have far less waste since 50 times more fuel would be burned generating energy. Molten salt reactors are even more efficient and could burn 99% of the uranium and plutonium in the reactor.

Increasing the current level of nuclear power in the world by 450 times would achieve the 1000 trillion kwh level. Increasing the efficiency of so that fuel usage is reduced by 30 to 98 times and being able to use thorium as well as uranium would ensure that there is sufficient nuclear fuel for the 5-15 times more per year that would be needed. There is uranium in seawater and Japanese researchers have been able to extract kilograms of it. It would cost more but fuel costs are only a small percentage of a nuclear plants operation.


2. Eradicate death [A Jones term]: Achieving actuarial escape velocity [which is not eradicating death but radical life extension] whereby life expectancy increases at greater than one year for each year that passes. No age related disease caused deaths. An increased level of increased physical regeneration and restoration. Really bad accidents or destructive weapons would still be able to kill. Advanced technology could create a precise copy of a person, but whether this will be done for ethical and societal reasons or whether the copy is the person is not discussed. A copy of "the mind" could be created in another substrate (ie. not a flesh and blood person but a computer than simulates "the mind").

Calorie restriction mimicking drugs could be available within five years according to a leading researcher and should provide 3-13 years of increased life span

Treatments to boost the human immune system against cancer and effective and cheap early detection of cancer cells will enable a massive decrease in cancer deaths.

The SENS project has raised over ten million dollars and is launching projects for each of the seven parts of the initial program to substantial extend human lives. This would be a major first step on the actuarial escape velocity path.

Regenerative medicine is making substantial advances with stem cells, tissue generation, and increasing the regenerative capability in humans to be more like salamanders (able to regrow limbs.) This research is well funded by the US defence department with the AFIRM (Armed Forces Institute of Regenerative Medicine funded for $250 million for five years) project.

3. Eliminate the bungled mechanisms that introduce imperfections into the human body: Enhance various performance aspects of the human body. Various medical and mechanical enhancements will be discussed which will be significant advances to existing performance enhancement.

Effective and safe myostatin inhibition will likely be developed which will enable most people to become several times stronger and closer to the best levels achievable now (one in one million people already have myostatin inhibited and it is four times as effective as high doses of steroids).

Cognitive enhancement is already here and will become more effective.

Craig Venter, billionaire and enabler of new gene therapy and synthetic biology technology, has indicated that very strong cognitive enhancement is possible, desirable and a goal that he wants to achieve.

From the Eric Drexler website - things that MNT would enable.
- desktop computers with a billion processors
- inexpensive, efficient solar energy systems
- medical devices able to destroy pathogens and repair tissues
- materials 100 times stronger than steel

4. Blood stream robots or achieving the goals (cellular surgery and repair) for which blood stream robots were proposed using other means. [medical devices able to destroy pathogens and repair tissues]

Nanoparticles, existing blood stream robots and guideable containers and cellular repair are being proven and people are working to improve and deploy them.

5. Materials 100 times stronger than steel [cheap and commonly used] : Production or access to diamond and carbon nanotubes increased by 1000 times and using diamond as a primary material for house sized objects and for electronics.

Carbon nanotube production will be ramped up which will become very cheap and will be deployed widely

Very large (multi-carat) diamonds can be produced very fast since 2005 Current methods can produce, three-dimensional growth of colorless single-crystal diamond in the inch-range (~300 carat) is achievable. Large scale production and scaling up diamond creation is an active and well funded area.

6. Open access to space [within the solar system for human and robotic travel and small probes up to a significant fraction of light speed for interstellar access]

Ten near term developments for greatly improved space access were covered here

Mirrored laser arrays are achievable with refinement of current technology as is nuclear propulsion.

7. Pollution "elimination" : Reduction of pollution into the environment and nearly complete elimination of deaths caused by pollution.

The use of the uranium hydride and molten salt reactor would greatly reduce the use of fossil fuels.

This sites proposed energy plan is a fast, affordable, and low technology development risk path to eliminating fossil fuels and enabling abundant clean energy.

8. Desktop computers with one billion processors (or performance greater than one billion of todays processors)

500 cores in new teraflop chips for less than $200 for the processor.

Berkeley and Tensilica already working towards energy efficient and affordable exaflop computers for the 2015-2017 timeframe

Design conferences have been held to work out details on zettaflop computers

9. Shape changing functional devices like utility fog

Claytronics has been funded by Intel.


Precise 3 dimensional manufacturing is progressing

Conclusion
So how much of some of the key goals of a transhuman singularity can be achieved without fullblown molecular nanotechnology, AGI or fusion ? Quite a bit. which is why the real deal with molecular nanotechnology, AGI and fusion will be really impressive. The mundane technological singularity shows the kinds of societal shifts that will be needed in order to fully take advantage of the upside. A lot of systems and processes have to be redesigned. The mundane singularity is 100 to 1000 times faster in terms of production and various capabilities.

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June 18, 2008

Acoustic shield design for sonar invisibility


Sound shield: An acoustic cloak comprising alternating layers of sound-scattering materials should make objects invisible to sonar--and insulated from sound. In this computer-generated image, a cylinder (green circle) is coated with 200 layers of such a material, which was found to be the optimal design. Sound waves moving from left to right (their peaks and troughs are represented by red and blue lines) flow past the object and reform on the other side with no distortion.
Credit: New Journal of Physics

From Technology Review: Engineers have designed a material that redirects sounds and could be used in buildings to shield them from noises. The sound-shielding material, which, if actually made, would be the first acoustic cloaking device, could also be useful in hiding military ships and other vessels from sonar. Engineers led by José Sánchez-Dehesa at the Polytechnic University of Valencia, in Spain, have created a plan for making an acoustic shield, using alternating layers of two different materials. These materials would comprise arrays of sonic crystals--patterns of small rods made of aluminum or other materials that allow some sound waves to pass while blocking the passage of others. This is follow up work related to metamaterials that are being developed for superlenses and optical invisibility.

Sánchez-Dehesa has modeled a two-dimensional acoustic cloak but says that extrapolating his work to three dimensions should be straightforward. "We're proposing a cloak for any shape," he says. Hiding warships from sonar is one possible application. But Sánchez-Dehesa is interested in the problem of noise generally. "In principle," he says, "it's possible to make this cloak very thin," on the order of centimeters. "If we're able to design a wall to put in a house to screen external noise, it would be very nice." Cummer imagines columns for concert halls that do structural work but, acoustically, are effectively not there.

Unlike light cloaks, which can shield objects from light of only one frequency, acoustic cloaks should be able to shield an object to a broad range of frequencies. The speed of sound, however, is not a universal constant, so it should be possible to craft broadband acoustic cloaks. [Speculation: Similar principles could work for shielding against earthquake waves through the ground]


Acoustic cloaking in two dimensions: a feasible approach

This work proposes an acoustic structure feasible to engineer that accomplishes the requirements of acoustic cloaking design recently introduced by Cummer and Schurig (2007 New J. Phys. 9 45). The structure, which consists of a multilayered composite made of two types of isotropic acoustic metamaterials, exactly matches the conditions for the acoustic cloaking. It is also shown that the isotropic metamaterials needed can be made of sonic crystals containing two types of material cylinders, whose elastic parameters should be properly chosen in order to satisfy (in the homogenization limit) the acoustic properties under request. In contrast to
electromagnetic cloaking, the structure here proposed verifies the acoustic cloaking in a wide range of wavelengths; its performance is guaranteed for any wavelength above a certain cutoff defined by the homogenization limit of the sonic crystal employed in its fabrication.

They present an acoustic cloak that could be physically realizable. In brief, the proposed cloak is based on a multilayered structure consisting of two layers with the same thickness and made up of two different acoustic isotropic metamaterials. These metamaterials are built with sonic crystals (i.e. periodic arrays of sonic scatterers) based on two types of elastic cylinders that have to accomplish certain requirements on their mass density and effective sound speed. Numerical experiments based on multiple scattering method are presented to support the exact performance of the proposed cloak.
The paper is organized as follows. First, in section 2, we review the solution in the previous paper and report our approach to get the acoustic cloaking. Numerical experiments demonstrating the performance and properties of the proposed cloak are also presented and discussed. Section 3 describes the recipe to build the metamaterials needed to fabricate the multilayered cloak making it physically feasible. Finally, the work is summarized in section 4.

FURTHER READING
Jose Sanchez-Dehesa is one of the researchers that developed the new acoustic cloak design

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June 17, 2008

Carbon nanotube producing companies





Surveying the carbon nanotube market, the leaders in large scale production are Baytubes, Hyperion Catalysis International and Nanocyl. Along with Bayer and Hyperion, other leading producers include France's Arkema, Belgium's Nanocyl, Iljin Nanotech in South Korea, and Shenzhen Nanotech Port in China. Japan's Mitsui has a joint venture with Hodogaya Chemical for nanotube R&D, production, and distribution. This will look at these and other competitors, some future expansion plans and the main process that is used to get to larger scale production. Expanded production will bring down the price significantly for carbon nanotubes and lower price will make more applications economical.


Baytubes are in the process of constructing a new production line of 200 metric tons that we expect to be on-stream by 2009," Schmid says. Depending on the success of that operation, the Bayertubes vision is to have 3,000 metric tons of capacity in place by 2011.




Bayertubes uses a catalytic chemical vaper deposition on a fluidized bed process to produce large scale carbon nanotubes.


Hyperion Catalysis International of Cambridge, Mass, has partnered with Nanoledge in Germany to add Baytubes to epoxy resins used in sporting equipment. Bayer also has a supply agreement with FutureCarbon, which makes solvent-based nanodispersions and concentrates for processing into other materials.



Some markets for carbon nanotubes for Bayer Material Science (baytubes)

"We have done the dispersion step and sell concentrates or plastics containing the nanotubes, typically in concentrations of 15–20% by weight," Collins says. Because nanotubes are strong, but extremely lightweight, and can be highly electrically conductive, the final loading in a plastic part may be just 2–5%, or even less.

In its more than 20 years, Hyperion has seen small- and large-scale competitors emerge; about 35 MWNT suppliers can be found on supplier lists. Along with Bayer and Hyperion, other leading producers include France's Arkema, Belgium's Nanocyl, Iljin Nanotech in South Korea, and Shenzhen Nanotech Port in China. Japan's Mitsui has a joint venture with Hodogaya Chemical for nanotube R&D, production, and distribution.

"Nanotubes are not yet a commodity, and it's not enough just to 'buy nanotubes,'" Collins remarks in reference to the emergence of importers that sell inexpensive tubes from other sources. "We manufacture and sell at an attractive price based on the volume that is purchased. It's not our intent—and we hope it's not our
competitors'—to sell product based on price. It should be based on performance."

Cnano Technology, Menlo Park, Calif., company was founded in 2006 with a plan to change the economics of nanotube production and advance applications using extremely pure nanotubes. Cnano has what it calls a "novel hybrid technology" for low-cost MWNT production and a manufacturing site in China. In July, CMEA Ventures, Pangaea Ventures, and WI Harper invested a combined $6 million in the company.

Catalytic Materials of Pittsboro, N.C., has a patented process for making high-purity MWNTs. And San Jose, Calif.-based Ahwahnee Technology claims it can supply large-scale quantities of raw, treated, or premixed MWNTs. It offers MWNT kits to enable end users to test materials.

Among the leading large-scale producers is Nanocyl, formed five years ago as a spin-off of Belgium's University of Namur. In mid-2005, it started up a 15-kg-per-day reactor, and today it has an annual capacity of 40 metric tons for industrial, specialty, and research nanotubes.

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China's usage of cement

World cement usage in 2008 is 2.8 billion tons and is forecast to be 3.5 billion tons in 2012 China is using 1.3 billion tons in 2008 about 45% of the world total.

The cement usage is mainly driven by the fact that China is adding a one to one and half Los Angeles worth of city every year.

1.5%- 2% population migration from rural areas to small and large cities.
20 million to 30 million people into cities.

Building apartments, houses, roads, rail, airports, offices and factories.

China aims to increase its operational railway lines from 75,438 km in
2005 to more than 90,000 km by 2010.
So adding about 3000 km of rail per year.

Cement used for NYC subway was about 8000 cubic yards per mile. 11,260 tons per mile. (1.42 tons per cubic yard)

China has about 34,000 km of highways (2006), a number that's expected to more than double by 2020.

China now has 3.57 million km of roads, linking 88 percent villages and 98.5 percent rural towns.

About 13 million tons of cement is needed per 100,000 km of rural road. [33 pounds of cement per square yard of road, 7 yards wide, 1760 yards per mile = 203 tons per mile or 127 tons per km]

Some 270,000 km of rural highways will be built and upgraded in 2008. By comparison, 423,000 km of countryside highways were built or upgraded in 2007, a record high. So about 35 million tons of cement in 2008 and 60 million tons of cement in 2007.

The interstate highway in the US was responsible for 31% of the productivity increase in the USA after it was build and still boosts productivity

Construction non-residential buildings was two fifths of building construction in China

New construction will advance at a nine percent annual rate in real terms through 2011, continuing to outpace improvements and repairs. This trend will sustain through the next decade as China continues a high pace of economic development and industrialization. New construction also dwarfs improvements and repairs in size, accounting for over three-quarters of all construction expenditures in 2011.

China is building the equivalent of a 3 gorges dam every 2 years. They are putting dams on many other rivers. But the dam only used 10.8 million tons of cement. Less than 1% of one year's demand.


Construction expenditures in China are forecast to increase 8.8 percent annually through 2011 to ¥6.4 trillion in real (inflation-adjusted) terms. An ever expanding domestic economy, continuing endeavors to upgrade infrastructure, sustained strength in foreign investment funding, healthy demand for Chinese manufactured goods, and
further population and household growth will all work to drive construction market gains in China.

Nonbuilding construction expenditures will climb ten percent annually in real terms through 2011, fueled primarily by the government's efforts to modernize and expand China's physical infrastructure. These efforts include plans to upgrade the nation's rail system, to expand the national highway network -- known as the "7918 Network", and to enhance energy supplies through construction of new power plants such
as the Xiluodu Hydropower Plant and the Yangjiang Nuclear Power Station

Nonbuilding construction fastest growing end use

Cement consumption in nonbuilding construction will continue to post the best gains of any end-use segment, rising 6.8 percent yearly through 2010. Gains will be stimulated mainly by strong growth in China's nonbuilding construction activity. The government's continued efforts to modernize the country's infrastructure is exemplified by such massive projects as the South-North Water Diversion -- designed to redirect water to the northern plains from central and south China. This project, scheduled for completion in 2050, will result in annual cement consumption of over one million metric tons.

Nonresidential building will remain the largest end use for cement in China, growing at a 4.6 percent annual rate through 2010. Continued strength in foreign and private direct investment in commercial real estate development will help spur market gains.

Ready-mix concrete manufacturers in China will be the strongest market for cement, climbing at an annual pace of 12.9% to reach 194 million metric tons in 2008. Growth will be driven by the government's 2004 ban on onsite concrete production, enacted to help reduce environmental damage from onsite cement operations and improve the overall quality of concrete used in construction

FURTHER READING
McKinsey on China's urbanization

China's urban population will expand from 572 million in 2005 to 926 million in 2025 and hit the one billion mark by 2030. In 20 years, China's cities will have added 350 million people—more than the entire population of the United States today [17.5 million per year]. By 2025, China will have 219 cities with more than one million inhabitants—compared with 35 in Europe today—and 24 cities with more than five million people.


This site believes that China's urbanization is happening faster than official Chinese figures have indicated.

China is expecting 24 million new job seekers in cities and towns

Official figure was 577 million (44%) urban population in 2006

China was 37.7% urban in 2002 6.3% increase in 4 years. 1.6% per year increase. 21 million per year.

The Economist magazine talks about China's infrastructure splurge

Worldwide construction report

Construction machinery China is a booming business as is all construction related activity in China

China cement is more expensive than Thailand's cement

China's cement demand

China's CO2 emissions

Cement at wikipedia

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June 14, 2008

High Superconducting temperature predicted for boron-doped diamond and spinhole theory for all superconductors

There is superconducting in super hard boron doped diamond up to 45K according to a computational model.

T A Study calculates that boron-doped diamond (BC5) should be superconducting on up to temperatures of 45 K, which, if borne out in experiments, would make this class of material with the highest with the highest transition temperature into a superconducting state mediated by the passing of phonons.


A paperby Peter Wachter proposes that spin holes in anti -ferromagnetic clusters combine to make nonmagnetic bipolarons, which can condense and lead to superconductivity. (Cu, Pu and Fe high Tc superconductors: all the same mechanism.)

In conclusion, it has been shown that the parent materials of high Tc superconductors are antiferromagnets, where long - range magnetic order has been interrupted by 5 – 20% substitution of the magnetic ions by nonmagnetic ions. These nonmagnetic ions have been provoked by chemical doping, but are of the same kind as the magnetic ions, only in another valence state or another spin configuration. The remaining short – range antiferromagnetic clusters or fluctuations will surround such a spin hole with charge as a magnetic polaron. Two such polarons have an attractive interaction and form a boson nonmagnetic bipolaron. This can make a Bose condensation and lead to superconductivity, which has been shown in many papers by Alexandrov and Mott. We could show, that the same mechanism works for all three (Cu, Pu and Fe) high Tc superconducting systems.




A superconducting paper examines the issue of how the pairing of electrons works and which physical model might be a better explaination. A “pairing glue” in the Hubbard and t-J models is basically a question about the dynamics of the pairing interaction.

Synthesis and Microstructural Studies of Iron Based LaO1−xFxFeAs
Superconducting Materials

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Materialise a current leader in Rapid Manufacturing


Rapid manufacturing was used to make important components of a concept car. The Sintesi is a sports car with four doors and four seats, developed by a highly innovative approach: it does not consider the car as a shape that covers the mechanicals, but one that gives a shape to the mechanicals around the passengers, starting from the latter. (H/T to