November 07, 2012

New nanostructured material could lead to better armor

A new study by researchers at MIT and Rice University has shown that even lighter materials may be more capable and effective than Kevlar.

The key is to use composites made of two or more materials whose stiffness and flexibility are structured in very specific ways — such as in alternating layers just a few nanometers thick. The research team produced miniature high-speed projectiles and measured the effects they had on the impact-absorbing material.

The experimental work was conducted at MIT’s Institute for Soldier Nanotechnologies.

The team developed a self-assembling polymer with a layer-cake structure: rubbery layers, which provide resilience, alternating with glassy layers, which provide strength. They then developed a method for shooting glass beads at the material at high speed by using a laser pulse to rapidly evaporate a layer of material just below its surface. Though the beads were tiny — just millionths of a meter in diameter — they were still hundreds of times larger than the layers of the polymer they impacted: big enough to simulate impacts by larger objects, such as bullets, but small enough so the effects of the impacts could be studied in detail using an electron microscope.

This electron-microscope image of a cross-section of a layered polymer shows the crater left by an impacting glass bead, and the deformation of the previously even, parallel lines of the layered structure as a result of the impact. In this test, the layered material was edge-on to the impact. Comparative tests showed that when the projectile hit head-on, the material was able to resist the impact much more effectively. Image courtesy of the Thomas Lab, Rice University

Nature Communications - High strain rate deformation of layered nanocomposites

ABSTRACT - Insight into the mechanical behaviour of nanomaterials under the extreme condition of very high deformation rates and to very large strains is needed to provide improved understanding for the development of new protective materials. Applications include protection against bullets for body armour, micrometeorites for satellites, and high-speed particle impact for jet engine turbine blades. Here we use a microscopic ballistic test to report the responses of periodic glassy-rubbery layered block-copolymer nanostructures to impact from hypervelocity micron-sized silica spheres. Entire deformation fields are experimentally visualized at an exceptionally high resolution (below 10 nm) and we discover how the microstructure dissipates the impact energy via layer kinking, layer compression, extreme chain conformational flattening, domain fragmentation and segmental mixing to form a liquid phase. Orientation-dependent experiments show that the dissipation can be enhanced by 30% by proper orientation of the layers.

2 pages of supplemental material

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