This illustration shows lithium atoms (red) adhered to a graphene lattice that will produce electricity when bent, squeezed or twisted. Conversely, the graphene will deform when an electric field is applied, opening new possibilities in nanotechnology. Illustration: Mitchell Ong, Stanford School of Engineerin
ACS Nano - Engineered Piezoelectricity in Graphene
We discover that piezoelectric effects can be engineered into nonpiezoelectric graphene through the selective surface adsorption of atoms. Our calculations show that doping a single sheet of graphene with atoms on one side results in the generation of piezoelectricity by breaking inversion symmetry. Despite their 2D nature, piezoelectric magnitudes are found to be comparable to those in 3D piezoelectric materials. Our results elucidate a designer piezoelectric phenomenon, unique to the nanoscale, that has potential to bring dynamical control to nanoscale electromechanical devices.
“The physical deformations we can create are directly proportional to the electrical field applied. This represents a fundamentally new way to control electronics at the nanoscale,” said Evan Reed, head of the Materials Computation and Theory Group at Stanford and senior author of the study.
This phenomenon brings new dimension to the concept of ‘straintronics,’ he said, because of the way the electrical field strains—or deforms—the lattice of carbon, causing it to change shape in predictable ways.
“Piezoelectric graphene could provide an unparalleled degree of electrical, optical or mechanical control for applications ranging from touchscreens to nanoscale transistors,” said Mitchell Ong, a post-doctoral scholar in Reed’s lab and first author of the paper.
Using a sophisticated modeling application running on high-performance supercomputers, the engineers simulated the deposition of atoms on one side of a graphene lattice — a process known as doping — and measured the piezoelectric effect.
They modeled graphene doped with lithium, hydrogen, potassium and fluorine, as well as combinations of hydrogen and fluorine and lithium and fluorine on either side of the lattice. Doping just one side of the graphene, or doping both sides with different atoms, is key to the process as it breaks graphene’s perfect physical symmetry, which otherwise cancels the piezoelectric effect.
The results surprised both engineers.
“We thought the piezoelectric effect would be present, but relatively small. Yet, we were able to achieve piezoelectric levels comparable to traditional three-dimensional materials,” said Reed. “It was pretty significant.”
The researchers were further able to fine tune the effect by pattern doping the graphene—selectively placing atoms in specific sections and not others.
“We call it designer piezoelectricity because it allows us to strategically control where, when and how much the graphene is deformed by an applied electrical field with promising implications for engineering," said Ong.
While the results in creating piezoelectric graphene are encouraging, the researchers believe that their technique might further be used to engineer piezoelectricity in nanotubes and other nanomaterials with applications ranging from electronics, photonics, and energy harvesting to chemical sensing and high-frequency acoustics.
“We’re already looking at new piezoelectric devices based on other 2D and low-dimensional materials, hoping they might open new and dramatic possibilities in nanotechnology,” said Reed.
5 pages of supplemental material
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