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January 13, 2012

Particle-free silver ink prints small, high-performance electronics

University of Illinois materials scientists have developed a new reactive silver ink for printing high-performance electronics on ubiquitous, low-cost materials such as flexible plastic, paper or fabric substrates.

Electronics printed on low-cost, flexible materials hold promise for antennas, batteries, sensors, solar energy, wearable devices and more. Most conductive inks rely on tiny metal particles suspended in the ink. The new ink is a transparent solution of silver acetate and ammonia. The silver remains dissolved in the solution until it is printed, and the liquid evaporates, yielding conductive features.

“It dries and reacts quickly, which allows us to immediately deposit silver as we print,” Walker said.

flexible silver electrode. Photo by S. Brett Walker. Reactive silver ink is airbrushed onto a thin, stretchy plastic film to make a flexible silver electrode.

Journal of the American Chemical Society - Reactive Silver Inks for Patterning High-Conductivity Features at Mild Temperatures




Reactive silver inks for printing highly conductive features (over 10,000 S/cm) at room temperature have been created. These inks are stable, particle-free, and suitable for a wide range of patterning techniques. Upon annealing at 90 °C, the printed electrodes exhibit an electrical conductivity equivalent to that of bulk silver.



The reactive ink has several advantages over particle-based inks. It is much faster to make: A batch takes minutes to mix, according to Walker, whereas particle-based inks take several hours and multiple steps to prepare. The ink also is stable for several weeks.

The reactive silver ink also can print through 100-nanometer nozzles, an order of magnitude smaller than particle-based inks, an important feature for printed microelectronics. Moreover, the ink’s low viscosity makes it suitable for inkjet printing, direct ink writing or airbrush spraying over large, conformal areas.

“For printed electronics applications, you need to be able to store the ink for several months because silver is expensive,” Walker said. “Since silver particles don’t actually form until the ink exits the nozzle and the ammonia evaporates, our ink remains stable for very long periods. For fine-scale nozzle printing, that’s a rarity.”

The reactive silver ink boasts yet one more key advantage: a low processing temperature. Metallic inks typically need to be heated to achieve bulk conductivity through a process called annealing. The annealing temperatures for many particle-based inks are too high for many inexpensive plastics or paper. By contrast, the reactive silver ink exhibits an electrical conductivity approaching that of pure silver upon annealing at 90 degrees Celsius.

“We are now focused on patterning large-area transparent conductive surfaces using this reactive ink,” said Lewis, who also is affiliated with the Beckman Institute for Advanced Science and Technology, the Micro and Nanotechnology Lab and the department of chemical and biomolecular engineering at the U. of I.

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