In a June communication to the Journal of Materials Chemistry, the NIU researchers report on a new method that converts carbon dioxide directly into few-layer graphene (less than 10 atoms in thickness) by burning pure magnesium metal in dry ice.
Journal of Materials Chemistry - Conversion of carbon dioxide to few-layer graphene
Burning magnesium metal in dry ice resulted in few-layer nanosheets of graphene in high yields. These carbon nanomaterials were characterized by Raman spectroscopy, energy-dispersive X-ray analysis, X-ray powder diffraction and transmission electron microscopy. This work provides an innovative route for producing one of the most promising carbon nanostructures by capturing carbon dioxide that is popularly known as the greenhouse gas.
“It is scientifically proven that burning magnesium metal in carbon dioxide produces carbon, but the formation of this carbon with few-layer graphene as the major product has neither been identified nor proven as such until our current report,” said Narayan Hosmane, a professor of chemistry and biochemistry who leads the NIU research group.
“The synthetic process can be used to potentially produce few-layer graphene in large quantities,” he said. “Up until now, graphene has been synthesized by various methods utilizing hazardous chemicals and tedious techniques. This new method is simple, green and cost-effective.”
Hosmane said his research group initially set out to produce single-wall carbon nanotubes. “Instead, we isolated few-layer graphene,” he said. “It surprised us all.”
“It’s a very simple technique that’s been done by scientists before,” added Amartya Chakrabarti, first author of the communication to the Journal of Materials Chemistry and an NIU post-doctoral research associate in chemistry and biochemistry. “But nobody actually closely examined the structure of the carbon that had been produced.”
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