This filament containing about 30 million carbon nanotubes absorbs energy from the sun as photons and then re-emits photons of lower energy, creating the fluorescence seen here. The red regions indicate highest energy intensity, and green and blue are lower intensity. Image: Geraldine Paulus
Using carbon nanotubes (hollow tubes of carbon atoms), MIT chemical engineers have found a way to concentrate solar energy 100 times more than a regular photovoltaic cell. Such nanotubes could form antennas that capture and focus light energy, potentially allowing much smaller and more powerful solar arrays. The nanotube bundles described in the Nature Materials paper lose about 13 percent of the energy they absorb, but the team is working on new antennas that would lose only 1 percent.
Instead of having your whole roof be a photovoltaic cell, you could have little spots that were tiny photovoltaic cells, with antennas that would drive photons into them. The new antennas might also be useful for any other application that requires light to be concentrated, such as night-vision goggles or telescopes.
Solar panels generate electricity by converting photons (packets of light energy) into an electric current. Strano’s nanotube antenna boosts the number of photons that can be captured and transforms the light into energy that can be funneled into a solar cell.
The antenna consists of a fibrous rope about 10 micrometers (millionths of a meter) long and four micrometers thick, containing about 30 million carbon nanotubes. Strano’s team built, for the first time, a fiber made of two layers of nanotubes with different electrical properties — specifically, different bandgaps.
In any material, electrons can exist at different energy levels. When a photon strikes the surface, it excites an electron to a higher energy level, which is specific to the material. The interaction between the energized electron and the hole it leaves behind is called an exciton, and the difference in energy levels between the hole and the electron is known as the bandgap.
The inner layer of the antenna contains nanotubes with a small bandgap, and nanotubes in the outer layer have a higher bandgap. That’s important because excitons like to flow from high to low energy. In this case, that means the excitons in the outer layer flow to the inner layer, where they can exist in a lower (but still excited) energy state.
Therefore, when light energy strikes the material, all of the excitons flow to the center of the fiber, where they are concentrated. Strano and his team have not yet built a photovoltaic device using the antenna, but they plan to. In such a device, the antenna would concentrate photons before the photovoltaic cell converts them to an electrical current. This could be done by constructing the antenna around a core of semiconducting material.
The interface between the semiconductor and the nanotubes would separate the electron from the hole, with electrons being collected at one electrode touching the inner semiconductor, and holes collected at an electrode touching the nanotubes. This system would then generate electric current. The efficiency of such a solar cell would depend on the materials used for the electrode, according to the researchers.
Strano’s team is the first to construct nanotube fibers in which they can control the properties of different layers, an achievement made possible by recent advances in separating nanotubes with different properties. “It shows how far the field has really come over the last decade,” says Michael Arnold, professor of materials science and engineering at the University of Wisconsin at Madison.
Solar cells that incorporate carbon nanotubes could become a good lower-cost alternative to traditional silicon solar cells, says Arnold. “What needs to be shown next is whether the excitons in the inner shell can be harvested and converted to electrical energy,” he says.
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