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February 25, 2010

New Lithium Sulfide Batteries Could have Four times the Specific Energy of Lithium Ion Batteries

Nanoletters - New Nanostructured Li2S/Silicon Rechargeable Battery with High Specific Energy The Lithium Sulfide batteries theoretically can have four times the specific energy of lithium ion batteries and have been experimentally produced at 150% the specific energy of lithium ion.

Rechargeable lithium ion batteries are important energy storage devices; however, the specific energy of existing lithium ion batteries is still insufficient for many applications due to the limited specific charge capacity of the electrode materials. The recent development of sulfur/mesoporous carbon nanocomposite cathodes represents a particularly exciting advance, but in full battery cells, sulfur-based cathodes have to be paired with metallic lithium anodes as the lithium source, which can result in serious safety issues. Here we report a novel lithium metal-free battery consisting of a Li2S/mesoporous carbon composite cathode and a silicon nanowire anode. This new battery yields a theoretical specific energy of 1550 Wh kg−1, which is four times that of the theoretical specific energy of existing lithium-ion batteries based on LiCoO2 cathodes and graphite anodes (410 Wh kg−1). The nanostructured design of both electrodes assists in overcoming the issues associated with using sulfur compounds and silicon in lithium-ion batteries, including poor electrical conductivity, significant structural changes, and volume expansion. We have experimentally realized an initial discharge specific energy of 630 Wh kg−1 based on the mass of the active electrode materials.



14 pages of supplemental information



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