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December 08, 2009

At Stanford, nanotubes + ink + paper = instant battery

Dip an ordinary piece of paper into ink infused with carbon nanotubes and silver nanowires, and it turns into a battery or supercapacitor. Crumple the piece of paper, and it still works. Stanford researcher Yi Cui sees many uses for this new way of storing electricity. They also believe it will be low cost and could be commercialized quickly.

Simply coating a sheet of paper with ink made of carbon nanotubes and silver nanowires makes a highly conductive storage device, said Yi Cui, assistant professor of materials science and engineering.

"Society really needs a low-cost, high-performance energy storage device, such as batteries and simple supercapacitors," he said.

"This technology has potential to be commercialized within a short time," said Peidong Yang, professor of chemistry at the University of California-Berkeley. "I don't think it will be limited to just energy storage devices," he said. "This is potentially a very nice, low-cost, flexible electrode for any electrical device."

Cui predicts the biggest impact may be in large-scale storage of electricity on the distribution grid. Excess electricity generated at night, for example, could be saved for peak-use periods during the day. Wind farms and solar energy systems also may require storage.

Cui's work is reported in the paper "Highly Conductive Paper for Energy Storage Devices," published online this week in the Proceedings of the National Academy of Sciences.

"These nanomaterials are special," Cui said. "They're a one-dimensional structure with very small diameters." The small diameter helps the nanomaterial ink stick strongly to the fibrous paper, making the battery and supercapacitor very durable. The paper supercapacitor may last through 40,000 charge-discharge cycles – at least an order of magnitude more than lithium batteries. The nanomaterials also make ideal conductors because they move electricity along much more efficiently than ordinary conductors, Cui said.






His new research shows that a paper battery is more durable because the ink adheres more strongly to paper (answering the question, "Paper or plastic?"). What's more, you can crumple or fold the paper battery, or even soak it in acidic or basic solutions, and the performance does not degrade. "We just haven't tested what happens when you burn it," he said.

The flexibility of paper allows for many clever applications. "If I want to paint my wall with a conducting energy storage device," Cui said, "I can use a brush." In his lab, he demonstrated the battery to a visitor by connecting it to an LED (light-emitting diode), which glowed brightly.

A paper supercapacitor may be especially useful for applications like electric or hybrid cars, which depend on the quick transfer of electricity. The paper supercapacitor's high surface-to-volume ratio gives it an advantage.




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